A new heterometallic lanthanide-titanium-organic compound: [Eu₂Ti₂(dip)₆(dig)₂(H₃O)₂]·solvent (1, dip = diphenylglycolic acid, dig = diglycolic acid) has been synthesized under solvothermal conditions. Compound 1 contains a tetra-nuclear {Eu₂Ti₂} unit with the mixed ligands of dip and dig. Compound 1 displays intense red luminescence. Furthermore, the IR, PXRD, UV-vis and TGA spectra were also studied.