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Coupling CO2 reduction and methanol oxidation toward energy-efficient formic acid production

Weiming Lai, Yangyang Wan*, Kai Yan*

https://doi.org/10.1016/j.cjsc.2026.100906

ABSTRACT

This work highlights the immense potential of coupled electrocatalysis for low-energy CO2 utilization and the production of value-added chemicals. By simultaneously converting CO2 and methanol into formic acid at both electrodes, the system effectively utilizes the energy from renewable electricity to generate a high-value product. The use of alloy catalysts to promote selective intermediate formation and suppress competing pathways plays a crucial role in the success of the system, providing a clear example of how material design can overcome the limitations of conventional catalytic processes. The integration of CO2 reduction with methanol oxidation represents a novel approach to coupled electrocatalysis that maximizes the potential of both reactions, offering a path toward more efficient and sustainable chemical processes. As the field continues to evolve, such innovative strategies will be essential in realizing the full potential of electrochemical CO2 utilization for a sustainable future.



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