Just Accepted
Just Accepted
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ArticleLattice solvent-modulated multicolor photochromism in a donor-acceptor type iodoargentate hybridTanlai Yu*, Le Cen, Yaxin Cheng, Guoshuai Zhang, Dayi Guo, Lei Wu, Xufeng Yang, Zhiyu Zhang, Cuilin Yang, Huan Zhang, Wenjiao Li, Yunlong Fu*, Jiang Liu*, Yong Yan*
Multicolor Photochromism; Electron donor-acceptor system; Iodoargentate hybridt; Lattice solvent-modulated; Erasable printing
ABSTRACT
A novel electron donor-acceptor (EDA)-type haloargentate hybrid, [(2-Bz-pyH)(Ag5I6)]·MeCN, has been synthesized, which was found to display rare lattice solvent-modulated multicolor photochromic performance in the same EDA system. -
Engineering 2D/2D FeOOH/BiOCl S-scheme heterojunction toward efficient and stable tetracycline photodegradationWanxin Hu, Yan Shi, Junxia Yu, Haiyang Shi*, Yingping Huang, Ruiping Li*
S-scheme heterojunction; BiOCl; Photocatalysis; Charge separation; Structural stability
ABSTRACT
Engineering FeOOH/BiOCl S-scheme heterojunction photocatalyst exhibits excellent efficiencies of photocarrier separation and TC degradation, improving the structural stability and photocatalytic activity of BiOCl. -
ReviewFluorene chemistry as a design platform for polymeric HTLs: Substituent control and core linkages in perovskite photovoltaicsYujin Li, Paramaguru Ganesan*, Abd. Rashid bin Mohd Yusoff, Simonetta Orlandi, Peng Gao*
Fluorene polymers; Polymeric HTLs; Inverted PSCs; C9 substitution; In situ polymerisation; Anchoring groups
ABSTRACT
This review highlights how C9 substitution patterns and core linkages in fluorene-based polymeric HTLs govern interfacial chemistry, charge transport, and stability, providing a structure–performance roadmap for efficient inverted perovskite solar cells -
PerspectiveDinitrogen fixation on transition metal complexes with flexible axial bondingXue-Lu Ma*, Jun-Bo Lu, Yuan Zhang, Ya-Fei Jiang, Jun Li *
ABSTRACT
This perspective illustrates how hemilabile axial bonding in transition metal complexes functions as a dynamic electron reservoir, regulating metal oxidation states and facilitating efficient dinitrogen fixation, guiding future catalyst design. -
ArticleEfficient uptake of Cs+ by a layered gallium oxalatophosphate with the clear insight into remediation mechanismWen Ma*, Tian-Yu Pan, Tian-Tian Lv, Yan-Ling Guo, Hai-Yan Sun, Rui-Ping Yang, Jun-Hao Tang, Ting-Hui Zhuang, Kai-Qiang Jing, Mei-Ling Feng*, Xiao-Ying Huang
Cesium removal; layered materials; oxalatophosphate; ion exchange; structural transformation
ABSTRACT
The efficient and selective capture of Cs+ ions is achieved by a gallium oxalatophosphonate and the capture mechanism is clearly “visualized” through single crystal structure analysis at the molecular level. -
ReviewCervical cancer imaging with organic small molecule NIR fluorophores: Design strategies and biomedical applicationsPachaiyappan Murugan*, Fang Yang, Loganathan Praburaman, Vijayapoopathi Singaravel, Meivelu Moovendhan, Chitrarasu Manikandan, Shi-Yong Liu*
ABSTRACT
In cervical cancer, rational molecular engineering of organic small molecules NIR fluorescent biomarkers enables tumor microenvironment-responsive imaging and theranostics. However, clinical translation necessitates the resolution of challenges related to stability, synthesis, specificity, and safety. -
ArticleHydrogen migration induced magnetic phase transitions in two-dimensional Fe-porphyrinoid metal-organic frameworksChao Jia, Min Ren, Yingdi Jin*, Xingxing Li*
ABSTRACT
The MOF constructed from Fe and diradical porphyrinoid molecules enables switching between ferromagnetic and ferrimagnetic states through hydrogen migration at the porphyrinoid center. -
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ReviewOrganic π-conjugated units as versatile building blocks for high-performance birefringent crystalsZhiyong Bai, Sangen Zhao*, Kang Min Ok*, Junhua Luo*
ABSTRACT
Research into high-performance birefringent crystals with birefringence values greater than 0.3 has grown rapidly in recent years. This article highlights recent progress in the development of birefringent crystals derived from organic π-conjugated building blocks. -
ReviewTMO-based SERS: Dual enhancement mechanisms and multi-functional analytical applicationsXiaoyu Song, Lei Xu, Xiangyu Meng, Yuening Wang, Mingjian Zhang, Aochi Liu, Jie Lin*, Xiaotian Wang*
ABSTRACT
TMO-based SERS uses CT and LSPR for signal enhancement, enables ultrasensitive detection of biomarkers, pollutants and catalytic intermediates, and addresses reproducibility via defect/interface engineering. -
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ArticleMOF derived Co–Mo2C heterojunctions with interfacial electronic modulation for oxygen reduction reaction and zinc-air batteriesDesheng Li#, Qin Li#, Peng Xu, Xingyu Guo, Heng Wu, Rui Liu*, Fei Tan*
ABSTRACT
MOF; Catalysis; Heterojunction; Oxygen reduction reaction; Zn-air batteries -
ReviewCrystalline porous organic frameworks: Emerging platforms for enzyme immobilization in biomedical applicationsXueting Hu, Lijia Zhao*, Tingting Liao, and Cheng-Peng Li*
ABSTRACT
This minireview summerizes the recent advancement of enzyme@COF and enzyme@HOF, particularly their chemistry and functionality, focusing on the interactions between COF and HOF and enzymes, and elaborates on the protective effects of various COF and HOF on enzymes. The construction of enzyme@COF and enzyme@HOF is of great significance for the application in biomedicine. Furthermore, this review discusses the disease diagnoses and drug delivery capabilities of enzyme@COF and enzyme@HOF as nanomedicines in diseases, and explores their potential for more applications in the medical field in the future.
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ArticleMOF-derived carbon-encapsulated ZnS/MnO porous microspheres for high-performance lithium storageJiamin Xiong1, Baiying Huang1, Yuling Zhang , Kaixin Zhou, Yuxuan Liu, Shengen Gong*, Zhiguang Xu*, Yongbo Wu, Akif Zeb*, Xiaoming Lin*
ABSTRACT
The synthetic methodology demonstrates a straightforward and efficient approach, wherein ZnS/MnO-D composites are fabricated via a sulfidation process followed by direct calcination, utilizing Zn-Mn-BDC as a sacrificial template. -
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ArticleExcitation-dependent tunable photoluminescence in CsCdCl3 all-inorganic perovskite for anti-counterfeitingGuojun Zhou#*, Qiqiong Ren#, Yanting Wang#, Nan Zhang, Yilin Mao, Pei Wang, Xian-Ming Zhang*
ABSTRACT
CsCdCl3 perovskite exhibits excitation-dependent reversible PL switching, enabled by competitive transitions between free excitons of [CdCl6]4− octahedra and self-trapped excitons of [Cd2Cl9]5− dimers. -
ReviewBorane cage hybrid supramolecular metal-organic frameworks (BSFs): Design, synthesis and gas separation performanceChengye Lou1, Yu Hu1, Yunjia Jiang*, Lingyao Wang*, Yuanbin Zhang*
ABSTRACT
This review provides an overview of the development history and design strategies of boron cage hybrid supramolecular metal-organic frameworks for gas separation.
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Short CommunicationEnhancing birefringence and second-harmonic generation response via aliovalent metal substitutionZhiwei Sun, Bingbing Wu, Xiaoli Wang, Qingran Ding*, Yanqiu Zhang, Xinjie Zhou, Sinan Tan, Ming Zhong, Sangen Zhao, Junhua Luo*
ABSTRACT
Aliovalent metal substitution effectively lowers structural dimensionality, thereby resolving the inherent birefringence-SHG trade-off.
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ArticleNuclear magnetic resonance-guided Monte Carlo/molecular dy-namics structure inference for amorphous solidsKangren Kong1, Zaiqiang Ma1, Yu Yin, Zhaoming Liu, Ruikang Tang*
ABSTRACT
We introduce a REDOR-guided MC/MD workflow that converts site-specific NMR dipolar distances and angles into chemically realistic atomistic models of amorphous solids, demonstrated on amorphous calcium carbonate/phosphate. -
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ArticleUnidimensional heterostructured LSCF-GDC nanofiber film as oxygen electrode for efficient solid oxide cellWeilin Kong#, Man Lian#, Tong Sheng, Yarui Wang, Lu Zou*, Kaisheng Xia, Jian Pu, Bo Chi, Yunfeng Tian*
ABSTRACT
Ordered LSCF-GDC fibrous framework is developed for multifunctional SOCs with Rp of 0.117 Ω cm2, power density of 1.482 W cm-2, and stable CO2 electrolysis (2.30 A cm-2) at 800°C. -
ReviewOrganometallic mechanically interlocked molecules featuring N-heterocyclic carbene ligands: Recent advances in synthesis and applicationsYi Li, Ye Lu*, Shi-Ping Yang
ABSTRACT
N-heterocyclic carbene (NHC) are emerging as powerful building blocks for mechanically interlocked molecules (MIMs). This review provides a comprehensive overview of this rapidly developing field, detailing the coordination-directed synthesis and unique architectures enabled by NHC ligands. -
ArticleMolecular tailoring strategies for the controlled assembly of high-nuclearity sulfide-bridged metal clustersLao-Bang Wang1, Yaoyao Peng1, Yu Fang*, Jian-Ping Lang*
ABSTRACT
A molecular tailoring and reassembly strategy yields high-nuclearity metal sulfide clusters with novel topologies and markedly enhanced third-order nonlinear optical responses. -
ArticleInterface engineering of Co9S8/Ni3S2 heterojunction with robust stability for boosting peroxymonosulfate activationXiaohan Wang, Xue Guo, Zhuo Song, Chen Guan, Chengyu Yang, Tianyang Li, Yukun Zhu*, Yan Xu*
ABSTRACT
The interface engineering of novel Co9S8/Ni3S2 heterojunction was synthesized for efficient tylosin degradation with robust stability in the presence of peroxymonosulfate. -
ArticleAg(Te2O3)(PO4): The first Ag-containing phosphate-tellurite non-linear optical crystal featuring novel zigzag layered structurePiao Tang, Xin Wen, Jindong Chen, Ning Ye, Guang Peng*
ABSTRACT
The First Ag-containing phosphate-tellurite crystal, Ag(Te2O3)(PO4), was synthesized based on the functional group composite strategy, which exhibits a record SHG response of 2.1 × KH2PO4 among all reported phosphate-tellurites. -
An Al-based metal‒organic framework with multiple gates for highly efficient separation of benzene/cyclohexene/cyclohexaneWen-Yu Su1, Fang-Di Dong1, Zi-Luo Fang, Zhi-Shuo Wang, Mu-Yang Zhou, Xi Feng, Xiao-Tong Lu, Rong-Hua Wang, Xing-Yu Li, and Dong-Dong Zhou*
ABSTRACT
An Al-based metal‒organic framework achieves highly efficient separation of benzene/cyclohexene/cyclohexane, by virtue of multiple types of gates controlled by organic fragments and/or inorganic clusters in the quasi-three-dimensional pores. -
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ArticleUltrasonic cutting strategy yields lanthanide organic nanochains with bright emission: thermally enhanced luminescence and bio-optical imagingFan Yang, Guan‐Huang Zhang, Hai-Ling Wang*, Wen-Wen Qin, Zhong-Hong Zhu*, Fu-Pei Liang, Hua-Hong Zou*
ABSTRACT
Efficient ultrasonic cutting of one-dimensional chain-shaped Ln-MOFs obtained nanochains with a size suitable for cell imaging, realizing the application of chain-shaped Ln-MOFs in optical imaging of living cells. -
![Exploration and development of anthracene-containing supramolecular assemblies and their [4 + 2] photooxygenation 2025.100765](/Site/default/Uploads/20251013/未标题-3[499].png "Exploration and development of anthracene-containing supramolecular assemblies and their [4 + 2] photooxygenation 2025.100765")
ReviewExploration and development of anthracene-containing supramolecular assemblies and their [4 + 2] photooxygenationChaochao Fan*, Yue Wang, Dan Zhang, Wei Zuo, Wenxiong Zhang, Chuandong Jia*
ABSTRACT
Based on the coordination-driven self-assembly, the discrete, polymeric, and anion-directed anthracene-containing supramolecular assmblies realize the capture and release of 1O2 via reversible [4 + 2] photooxygenation. -
ArticleOne-dimensional (C12H12N)3Cu3I6 for high-performance direct X-ray detectionPan Gao, Qingzheng Kong, Ying Sun, Qian Ma, Qi Wang, Zeyu Guo, Ledi Li, Bingbing Li, Jingwei Xu, Xiaomei Jiang*, Zhaolai Chen
ABSTRACT
An environmentally friendly one-dimensional (C12H12N)3Cu3I6 single crystal-based detector achieved high sensitivity of 1464 μC·Gy-1·cm-2 in X-ray detection. -
ArticleIr/Ni-N-C electrocatalyst with promoted CO-tolerance towards alkaline hydrogen oxidation reactionYiming Jin, Mingming Pan, Wei Luo*
ABSTRACT
A highly efficient Ir/Ni-N-C catalysts with promoted CO-tolerance were fabricated for alkaline hydrogen oxidation reaction. The unique electronic interaction and coordination effects induced by Ni-N-C substrates optimize the adsorption behavior towards the vital hydroxyl species, which lower the energy barrier of the sluggish water formation step and boost the CO oxidative desorption process simultaneously, accounting for their improved catalytic performance. -
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ArticleEnhancing the photocatalytic activity of crystalline g-C3N4 towards NO oxidation and CO2 reduction through K+-doping and cyano defect engineeringZhou Li, Mengxue Yu, Shixin Chang, Zhibin Huang, Zhenmin Cheng, Weibin Zhang, Sónia A.C. Carabineiro, Zhigao Xu, Kangle Lv*
ABSTRACT
K+-doped crystalline g-C3N4 with cyano defects (CNK) was facilely synthesized using KCl as a molten salt. The material exhibits enhanced photoreactivity due to the formation of a build-in electric field.
- Address: Fuzhou High & New Technology Industrial Zone, Shangjie, Minhou, Fuzhou, Fujian 350108, China
- Tel: (86)-591-63173769, 63173770
- E-mail: cjsc@fjirsm.ac.cn