Just Accepted
Just Accepted
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ArticleAnions-mediated interfacial-water regulation boosts C2+ selectivity for CO2 electroreduction over Cu-based catalystsTingting Gong, Zhen Liu, Wen Jin, Jiamei Li, Min Wang*, Luhua Jiang*
CO2 electrochemical reduction; Cu-based catalysts; Interfacial water; Anions; In-situ ATR-SEIRAS
ABSTRACT
Low-concentration anions in 1 M KOH elevate the strong interfacial-water structure proportion following F⁻ > Cl⁻ > Br⁻ > NO3⁻, yielding a volcano relation between C2+ selectivity and strongly hydrogen-bonded water fraction.
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ArticleSulfur-vacancy engineered SmCoO3/MnCdS S-scheme heterojunction for efficient photothermal-photocatalytic H2 evolutionYuanjin He, Hao Yang, Qiwei Guo, Bo Zhou, Xuqiang Hao*, Zhiliang Jin
S-scheme heterojunction; Photocatalytic hydrogen evolution; Vacancy engineering; Photothermal effect; Charge separation
ABSTRACT
A sulfur-vacancy engineered SmCoO3/MnCdS-Vs S-scheme heterojunction with photothermal effect was successfully constructed for boosting photocatalytic hydrogen evolution. -
ArticleModification of structure and electrical properties of antiperovskite Ni3FeN under high pressureTao Han, Yijie Zeng, Pengfei Tan, Meihuan Zhao, Yuxuan Liu, Man-Rong Li*
Antiperovskite nitride; High pressure; Structural phase transition; Electrical transport; Mechanical properties
ABSTRACT
High pressure induces a cubic-to-orthorhombic structural transition in Ni3FeN, accompanied by anomalous resistance rise and mechanical softening, revealing the intrinsic connection between crystal structure evolution and its electrical transport and mechanical behavior. -
ArticleBoosting H2S conversion with S-scheme Cd0.5Zn0.5S/TiO2 nanotube arrays photoanodeWenqi Wang, Xiajie Zhang, Ting Gao, Lin Ju*, Dongqiu Zhao*, Enzhou Liu*
Photoelectrocatalyst; H2S conversion; Cd0.5Zn0.5S; TiO2 nanotube; S-scheme heterojunction
ABSTRACT
S-scheme Cd0.5Zn0.5S/TiO2 nanotube photoanode enables efficient photoelectrocatalytic H2S splitting to H2 and sulfur. -
ReviewAdvances in copper-based catalysts for selective CO₂ electroreduction to C1 and C2 productsShen Wang, Yi Wei, Weijie Li, Chao Han*
CO2 electroreduction; Copper-based catalysts; Selectivity; Stability
ABSTRACT
This work elucidates key descriptors and mechanistic pathways governing Cu-based catalysts for selective CO2 reduction to C1/C2 products, highlighting design strategies and stability challenges. -
ArticleSynergistic modulation of steric hindrance and isomerization space for enhanced photo-regulated performance of metal-organic polyhedraShu Shi†, Mu-Yi Xu†, Yang Liu, Yu-Xia Li, Lin-Bing Sun*
ABSTRACT
Synopsis: Synergistic steric hindrance and isomerization space in (tBu-Azo)(LA)MOP enable efficient solid-state photoisomerization under UV/visible light. -
ArticleDefect-enhanced charge separation in ZnCdS/WS2 S-scheme heterojunctions: Engineering sulfur vacancies to facilitate photocatalytic H2 productionTuo Guo, Guojing Hu, Jiaxin Liu, Li Chen, Guangmin Ren*, Qingjie Guo*
Vs-WS2; ZnCdS; S vacancy; Photocatalytic hydrogen evolution; S-scheme heterojunction
ABSTRACT
Synergistic internal electric field and sulfur vacancies in S-scheme ZnCdS/Vs-WS2 heterojunction enable ultrahigh photocatalytic H2 evolution. -
ArticleAlkoxy chain-length engineering in heterometallic In-Sn-oxo clusters for nanolithographyZhaoke Jin, Weizhou Chen, Yifan Hou, Yuting Ye, Xiuzhen Wang, Xiaofeng Yi*, Jian Zhang*
In-Sn-oxo-clusters; Atomically precise structures; Tunable alkoxy chain-length; Solution processability; Nanolithography
ABSTRACT
This study reveals the critical role of ligands chain length in heterometallic In-Sn-oxo clusters, showing how precise ligand engineering controls solution behavior and patterning mechanism, ultimately unlocking high-resolution lithographic performance. -
ArticleBoosting efficient electrocatalytic CO2 reduction by two-dimensional polyoxometalate@metal-organic framework composites with asymmetric sitesTeng-Fei Yao, Guo-Ping Yang*, Yao-Yu Wang
Polyoxometalates; Metal-organic frameworks; Asymmetric coordination sites; Electrocatalytic CO2 reduction reaction
ABSTRACT
Two Ag-based POM@MOF composites with asymmetric bifunctional sites were synthesized. They synergistically activate CO2 and promote *COOH formation, thereby enhancing electrocatalytic CO2 reduction. -
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ArticleMetal-incorporated polymeric resists with tunable lithographic performance via complex-specific designXi Liang, Mei-Hua Xiong, Er-Xia Chen, Lu-Yao Hao, Jin-Xia Yang*, Jian Zhang*, Qipu Lin*
Non-chemically amplified resists; electron-beam lithography; organometal-incorporated polymers; EUV lithography; negative-tone photoresists
ABSTRACT
A new class of sulfonium-centered cationic polymers functionalized with monometallic Sn, Sb, or Bi complexes—denoted BP-Sn, BP-Sb, and BP-Bi—is introduced as non-chemically amplified negative-tone photoresists alongside a metal-free analogue (BP). Maintaining nearly identical backbones and varying only the metal center enables precise control over organometal-specific effects, allowing direct comparative assessment of how Sn, Sb, and Bi govern key lithographic parameters. Systematic investigation reveals distinct performance profiles: BP-Sb achieves the highest sensitivity, BP-Bi delivers superior resolution, and BP-Sn exhibits the sharpest contrast. -
ReviewRecent progress on multi-synergistic charge-transfer strategies for efficient triplet up-conversion in narrowband MR-TADF emittersZeng-Jiang Yue, Zheng-Yin Du*, Xunwen Xiao*, Xu-Feng Luo*
Multiple-resonance; Thermally activated delayed fluorescence; CT modulation; Synergistic channel interactions; OLED
ABSTRACT
This review summarizes multi-synergistic charge-transfer strategies in MR-TADF materials, highlighting how precise structural modulation of excited states enables efficient triplet up-conversion for narrowband OLEDs. -
Spin-state switching driven by divergent structural evolutions in a 3D spin-crossover materialMeng-Ling Wu†, Jun-Hui Liang†, Yan-Ru Chen, Kang Chen, Ze-Yu Ruan, Si-Guo Wu*, Wei-Zhao Cai*, Ming-Liang Tong*
Spin crossover; Pressure; Symmetry breaking; Stimuli-responsive; Spin-state regulation
ABSTRACT
A cyanide-bridged bimetallic coordination polymer featuring one-dimensional zigzag Ag chains with argentophilic interactions was synthesized, and exhibited divergent structural evolutions and spin-state regulation in response to thermal and pressure stimuli. -
ArticleUltramicroporous metal-incorporated HOF with tailored pore confinement for high-efficiency C2H2/CO2 sieving separationYingzhi He, Guangzu Xiong, Wenlei Yang, Yunjia Jiang, Jianbo Hu, Lingyao Wang, Chaoqun Bian*, Yuanbin Zhang*
ABSTRACT
An ultramicroporous metal-incorporated HOF with tailored pore confinement was prepared for high-efficiency C2H2/CO2 sieving separation with benchmark dynamic separation factors. -
Tuning effective conjugation via B←N orientation: High-mobility n-type isoindigo polymers for organic field-effect transistorsJingshu Tian, Haofeng Sun, Jiarui Li, Cheng Wang, Kun Yang, Qinqi Zhou, Kai-kai Liu*, Maning Liu*, Haichang Zhang*
B←N coordination chemistry; n-type conjugated polymers; Organic field-effect transistors (OFETs); Electron mobility; Backbone conformation
ABSTRACT
The vertical configuration of the B←N-coordinated units is conducive to backbone planarity and ordered molecular packing, consequently improving the electron transport mobility in OFETs. -
Hydroxyl-functionalized Ni7-cluster-based MOF for cost-effective acetylene separationYaqing Fan, Jiexi Guo, Rizhao Zhang, Bao Li*, Jia Li*
Metal-organic frameworks; C2H2/C2H4 separation; C2H2/CO2 separation; Acetylene recovery
ABSTRACT
A chemically stable Ni₇-cluster MOF is fabricated in this work. Pore microenvironment engineering endows the material with superior C₂H₂ separation and high-purity C₂H₂ recycling performance. -
ArticleMixing enthalpy-induced monodispersed Pb-Zr dual-atomic cata-lysts for efficient photocatalytic hydrogen peroxide productionWei Zhang#, Dan Liu#, Haishan Zhu#, Longzhou Jin, Shijie Li*, Fang Yang, Yihong Zhang*, Chunqiang Zhuang*
H2O2 production; Dual atom; Mixing enthalpy; Oxygen reduction reaction
ABSTRACT
Mixing enthalpy-driven PbZr dual-atom photocatalyst for efficient photocatalytic oxygen reduction -
Organic-inorganic zinc halide multiferroic designed by tetrahedral halogen engineeringYing Wang, Hong-Zhi Hu, Hao-Fei Ni, Guo-Tao Bai, Lei Pan, Hao-Ran Chen, Xiao-Xiao Chen, Lian-Jie Wu, Zunqi Liu*, Zhi-Xu Zhang*, Da-Wei Fu*
Multiferroic material; Halogen engineering
ABSTRACT
The first zinc-based organic-inorganic hybrid multiferroic (CTA)2ZnI4 is realized via tetrahedral halogen engineering. It elevates the Curie temperatures of the (CTA)2ZnX4 series and induces dual ferroelastic and ferroelectric properties.
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ArticleTernary sulfide/triazinyl COF S‑scheme photocatalyst: Enhanced H2O2 production and Fs‑TA mechanistic studyYue Zhao, Shu Lin*, Kezhen Qi*, Li Zhao*
COFs; Ternary sulfides; S-scheme; H2O2 production; fs-TA
ABSTRACT
A photocatalyst (CdIn2S4/COF) was designed for efficient photocatalytic hydrogen peroxide production, exhibiting high activity. fs-TA and KPFM revealed the charge transfer mechanism. -
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ArticleTopology-symmetry analysis and structure prediction in nonlinear optical AB4O6F (A = Na, K, Rb, Cs, NH4) and AAlB3O6F (A = K, Rb, Cs) polytypesOlga Reutova#, Wenqi Jin#, Congwei Xie, Junjie Li, Zhihua Yang*, Xueling Hou*, Shilie Pan
Fluorooxoborates; Second harmonic generation; Structure prediction; polytypism; Theory of symmetry; OD-theory; Density functional theory
ABSTRACT
New AB4O6F and AAlB3O6F polytypes predicted using topology-symmetry approach and first-principles calculations; decreasing SHG efficiency in polytypes could be caused by local pseudo-centrosymmetric layer stacking. -
ReviewEmerging halide perovskite ferroelectric semiconductors: Structural diversity, chemical design and optoelectronic applicationsYating You, Xiaoqi Li, Qianxi Wang, Xitao Liu*, Zhihua Sun*, Junhua Luo*
Ferroelectricity; Halide perovskite; Semiconductors; Spontaneous polarization; Photodetection; Ionizing radiation detection
ABSTRACT
Schematic of correlation among chemical diversity, chemical design, and optoelectronic applications of halide perovskite ferroelectric semiconductors. -
ArticleHighly selective glycerol electrooxidation assisted hybrid water electrolysis using a trifunctional heterojunction CoP/(Fe0.25Co0.75)3N catalystYuxiang Tang, Yong Zhang, Wenjun Qin, Xiaolin Wei, Yuxue Mo*, Haiqing Zhou*
Electrocatalyst; Non-noble; Water electrolysis; Glycerol oxidation reaction; Heterostructure
ABSTRACT
In the GOR-assisted hybrid electrolyzer, the CoP/(Fe0.25Co0.75)3N catalyst demonstrates more exceptional catalytic activity (1.43 V at 100 mA cm–2) than that of OER (1.59 V at 100 mA cm–2).
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ReviewRecent progress in amorphous metal halides for optoelectronicsShun-Shun Li , Kaifeng Wu*, Pengfei Cheng*
Amorphous materials; Metal halides; Polymeric metal halides; Glassy state
ABSTRACT
This review surveys amorphization strategies, structural characteristics, and structure-property relationships of amorphous metal halides, highlighting their emerging optoelectronic functionalities and application potential. -
![Enhanced tripling-performance in [C(NH2)3]4P2O7·H2O as UV non-linear optical material due to π-conjugated cation and hydrogen bonding intervention 2026.100904](/Site/default/Uploads/20260309/未标题-3[589].png "Enhanced tripling-performance in [C(NH2)3]4P2O7·H2O as UV non-linear optical material due to π-conjugated cation and hydrogen bonding intervention 2026.100904")
ArticleEnhanced tripling-performance in [C(NH2)3]4P2O7·H2O as UV non-linear optical material due to π-conjugated cation and hydrogen bonding interventionLei Wu, Enshen Wang, Bao Jiang, Xueyin Fu, Kechen Sun, Maierhaba Abudoureheman, Zhaohui Chen*, Qun Jing*, Yuhong Su
Nonlinear optical; Guanidinium; Dangling bonds; Hydrogen bond network; Cut-off edge
ABSTRACT
The hydrogen-bond network passivates O-centered dangling states and locks π-conjugated units into a corrugated, anisotropic lattice, delivering DUV transparency, strong SHG, and birefringence suitable for 266 nm phase matching. -
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ArticleHalogen effect on non-conventional organogel with controlled ultra-long room temperature phosphorescence and fast-responseShuzhan Chen, Yi Shi, Huayang Liang, Huamiao Lin, Peng Geng*, Dan Luo*, Haichuang Lan, Shuzhang Xiao*
Room-temperature phosphorescence; Non-conventional organogel; Halogen bonding; Stimuli-responsive; Dynamic anti-counterfeiting
ABSTRACT
Bromine-substituted gel with ultra-long room temperature phosphorescence shows an eight-fold enhanced phosphorescence quantum yield and thermal-responsive anti-counterfeiting. -
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ArticleSurface confined nano-copper synergistically promotes the tehydrogenation of cyclohexanol to cyclohexanoneXue Zhao*, Cuiyu Li, Qiao Ye, Hongqin Wang, Yicheng Zhang*, Nihong An*
Nano-copper; Biochar; Cyclohexanol; Cyclohexanone; Dehydrogenation
ABSTRACT
CuO and amorphous Cu were rapidly constructed by wet reduction at the interface of two-dimensional biochar, which synergistically promoted the highly selective conversion of cyclohexanol to cyclohexanone in a wide temperature range (240-270 °C), while taking into account the conversion rate, selectivity and stability.
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ArticleConstruction of S-scheme CuBi2O4/BiOI heterojunction with oxygen vacancy for efficient photocatalytic CO2-to-CH4 conversionWeina Shi, Leilei Zhang*, Ran Zhang, Baocheng Yang, Jiao Guo*, Xiaowei Guo, Haoran Ma*, Ji-Chao Wang*
S-scheme photocatalyst; CO2 reduction; Surface defect; Product selectivity; CuBi2O4/BiOI
ABSTRACT
S-Scheme heterojunction composed of flake-like BiOI on rod-like CuBi2O4 with oxygen vacancies enabled efficient photocatalysis of CO2-to-CH4 selective conversion in water vapor. -
ArticleEvaluation of bulk photochromic performance: A case study of RA-Ln-PONbWei-Chao Yang, Yi-Ying Li, Cai Sun*
Photochromism; Bulk materials; Performance evaluation
ABSTRACT
This work standardizes the performance evaluation metrics for bulk photochromic materials, providing an important methodological foundation for performance comparisons among different bulk materials. -
ReviewStructure-thermal transport relationships in polymers-based composites: Models, metrology, and microstructure controlMunshi Jasimuddin, Zhijie Wang, Jiajing Huang*, Jiawang Wen*, Yue Lin*
Thermally conductive polymer composites; Thermal conductivity; Structure-property relationships; Thermal metrology; Microstructure design; Thermal interface materials (TIMs)
ABSTRACT
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ArticleLigand functionalization boosts circularly polarized luminescence in chiral MOFsZhi-Wen Wang, Xiuzhen Wang, Yi-An Chen, Hong-Rui Zheng, Yu-Peng Han, Fei Wang*, Shumei Chen*, Shangda Li*, Jian Zhang
Metal-organic frameworks; Circularly polarized luminescence; Circularly polarized fluorescence energy transfer; Ligand functionalization
ABSTRACT
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ReviewPlasma-driven material synthesis and structural chemical engineering of silicon-based anodes for lithium-ion batteriesYuanjiang Dong+, Shiqi Bi+, Mengru Wang+, Zongxian Yang*, Xinnian Tian, Yurun Chen, Ziqi Sun, Renren Sun, Yuge Ouyang, Liuyang Bai*, Jishi Wei*, Fangli Yuan, Ming-Shui Yao*
Lithium-ion battery; Silicon-based anodes; Plasma technology; Material synthesis; Structural chemistry engineering
ABSTRACT
This review summarizes the research on plasma-assisted synthesis and modification of silicon-based anode materials, emphasizing how plasma alters material physicochemical properties and enhances electrochemical performance. -
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ArticleS-scheme GQDs/Bi24O31Br10 heterojunction boosts photocatalytic H2O2 production and tetracycline degradationMengqing Li, Changzhao Chen*, Qishen Wang, Kai Dai*
S-scheme heterojunction; Bifunctional photocatalyst; Photocatalytic H2O2 production; Antibiotic degradation; Charge separation
ABSTRACT
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ReviewModification of open metal sites in metal-organic frameworks for the enhancement of CO2 capture and alkane separationXufei Li, Junfa Fu, Weiqiu Huang*, Zhaoqiang Zhang*, Xiaofang Lv, Jiahao Kang, Jixing Xu, Jiahua Cheng, Yuhao Lu, Yitong Sun
MOFs; Open metal sites; Modified strategy; Stability; CO2 capture; Alkane separation
ABSTRACT
This review provides an overview of the modification of open metal sites in metal-organic frameworks for CO2 or alkanes separation. -
ArticleDirect synthesis of highly porous Cr-MOFs with hexatopic car-boxylate ligands for water adsorptionChaozhuang Xue, Yingying Zhang, Konggang Qu, Shuwen Gong, Huajun Yang*
Chromium(III) MOFs; Rigid-acs based pacs; Highly porous; Stable MOFs; Water adsorption
ABSTRACT
Novel pacs-type chromium(III) metal-organic frameworks with highly porosity and structural stability are obtained via a one-pot dual-modulator synthetic strategy. These Cr-pacs can be viewed as the partitioned structures of rigid acs frameworks, with the consideration of both size and symmetry matching between acs forming ligand (hexatopic carboxylate ligand) and partitioning ligand (tridentate pyridine ligand). -
Reviewg-C3N4-based S-scheme heterojunction photocatalyst and its applicationZhiwei Meng, Shasha Chen, Pingyu Yang, Yupeng Yan, Guanjie Jiang, Qin Zhang, Yang Li*
S-scheme heterojunctions; Carbon nitride (g-C3N4); Environmental application; Photocatalysis
ABSTRACT
Theoretical Basis and Application Scenarios of g-C3N4-Based S-scheme Heterojunction Photocatalysts -
ArticleEfficient charge separation of RF/CdTMT S-scheme photocatalyst with enhanced photocatalytic H2O2 productionYonghui Ma, Lei Ji*, Jinfeng Zhang*, Graham Dawson, Kai Dai*
S-scheme heterojunction; Photocatalytic H2O2 production; RF; CdTMT; Charge separation
ABSTRACT
RF/CdTMT S-scheme heterojunctions synthesized by an oil bath method facilitate charge separation, showing 15.15 and 3.01 times higher H2O2 yields than the pristine catalysts.
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